| 货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
|---|---|---|---|---|
| P293928-500mg |
500mg |
现货  |
| |
| P293928-2g |
2g |
现货 |
|
| 别名 | 乙酰丙酮钯(II)盐 | 双(2,4-戊二酮)钯(II) | 乙酰丙酮钯(II)，2,4-戊二酸钯(II) |
|---|---|
| 英文别名 | Bis(2,4-pentanedionato)palladium(II) | Palladium(II) acetylacetonate | Pd(acac)2 | Acetylacetone Palladium(II) Salt |
| 规格或纯度 | ≥99.95% metals basis |
| 英文名称 | Palladium acetylacetonate |
| 储存温度 | 避光,室温,充氩 |
| 运输条件 | 常规运输 |
| 产品介绍 |
产品应用： （Pd(acac)2）被用于以下研究： 制备单分散CuPd合金纳米颗粒（NPs）的典型高温有机溶液相方案 [(NHC)Pd(acac)L]复合物的制备（其中L=Me，NHC= N-杂环卡宾），这些复合物能有效催化活化芳基溴化物的Heck反应 作为芳基羧酸与芳基卤化物的脱羧交叉偶联反应的催化剂。 Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium. Product class Reaction type Chemical properties Chemical formula C10H14O4Pd Empirical formula [Pd(acac)2] Molecular weight 304.64 Metal Pd Theoretical metal content 35 Physical state powder Color yellow Metal purity 99.95 |
| PubChem SID | 504763837 |
|---|---|
| EC号 | 237-859-8 |
| 分子类型 | 小分子 |
| IUPAC Name | (Z)-4-hydroxypent-3-en-2-one;palladium |
| INCHI | InChI=1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/b2*4-3-; |
| InChi Key | BABLLCDZHABSRT-FDGPNNRMSA-N |
| Canonical SMILES | CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Pd] |
| Isomeric SMILES | C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.[Pd] |
| WGK Germany | 2 |
| PubChem CID | 5462715 |
| 分子量 | 304.64 |
| Beilstein号 | 4136188 |
| 溶解性 | Soluble in benzene and chloroform. |
|---|---|
| 敏感性 | 对光敏感 |
| 沸点 | 300 °C 在 0.1 百帕 |
| 熔点 | 200 - 251 °C |
| 分子量 | 306.650 g/mol |
| XLogP3 | |
| 氢键供体数Hydrogen Bond Donor Count | 2 |
| 氢键受体数Hydrogen Bond Acceptor Count | 4 |
| 可旋转键计数Rotatable Bond Count | 2 |
| 精确质量Exact Mass | 306.008 Da |
| 单同位素质量Monoisotopic Mass | 306.008 Da |
| 拓扑极表面积Topological Polar Surface Area | 74.600 Ų |
| 重原子数Heavy Atom Count | 15 |
| 形式电荷Formal Charge | 0 |
| 复杂度Complexity | 239.000 |
| 同位素原子数Isotope Atom Count | 0 |
| 定义的原子立体中心计数Defined Atom Stereocenter Count | 0 |
| 未定义的原子立体中心计数Undefined Atom Stereocenter Count | 0 |
| 定义的键立体中心计数Defined Bond Stereocenter Count | 2 |
| 未定义的键立体中心计数Undefined Bond Stereocenter Count | 0 |
| 所有立体化学键的总数The total count of all stereochemical bonds | 2 |
| 共价键合单元计数Covalently-Bonded Unit Count | 3 |
| 象形图 | GHS07 |
|---|---|
| 信号词 | Warning |
| 危险声明 |
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H228: 易燃固体 |
| 预防措施声明 |
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P337+P317: 如果眼睛刺激持续：寻求医疗帮助。 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。 P319: 如果你感到不适，请寻求医疗帮助。 |
| WGK Germany | 2 |
| 个人防护装备 | dust mask type N95 (US),Eyeshields,Gloves |
| Appearance(P293928) | Yellow to yellow-green powder or chucks |
|---|---|
| Purity(Based On Trace Metals Analysis) | |
| Proton NMR spectrum | Conforms to Structure |
| ICP: Confirms Pd Component | Confirmed |
通过匹配包装上的批号来查找并下载产品的 COA，每批产品都进行了严格的验证，您可放心使用！
| 批号(Lot Number) | 证书类型 | 日期 | 货号 |
|---|---|---|---|
 D2522339 |
分析证书 | 24-11-06 | P293928 |
| D2522340 |
分析证书 | 24-11-06 | P293928 |
| H2405576 |
分析证书 | 24-07-25 | P293928 |
| H2405577 |
分析证书 | 24-07-25 | P293928 |
| I2313484 |
分析证书 | 23-09-04 | P293928 |
| I2313485 |
分析证书 | 23-09-04 | P293928 |
| E2329234 |
分析证书 | 23-05-10 | P293928 |
| E2329236 |
分析证书 | 23-05-10 | P293928 |
| B2303502 |
分析证书 | 22-11-28 | P293928 |
| B2303503 |
分析证书 | 22-11-28 | P293928 |
| B2303504 |
分析证书 | 22-11-28 | P293928 |
| B2303505 |
分析证书 | 22-11-28 | P293928 |
| D2306092 |
分析证书 | 22-11-28 | P293928 |
| G2220056 |
分析证书 | 22-07-01 | P293928 |
| K2228271 |
分析证书 | 22-07-01 | P293928 |
| F2204637 |
分析证书 | 22-03-24 | P293928 |
| F2204638 |
分析证书 | 22-03-24 | P293928 |
| A2212356 |
分析证书 | 21-12-27 | P293928 |
| A2212373 |
分析证书 | 21-12-27 | P293928 |
¥259.90
| 1. Wenjie Xue, Binbin Zhao, Hongxia Liu, Xinqing Chen, Lei Liu. (2024) Ultralow Pd bimetallic catalysts boost (de)hydrogenation for reversible H2 storage. APPLIED CATALYSIS B-ENVIRONMENTAL, 343 (123574). [10.1016/j.apcatb.2023.123574] |
| 2. Cuicui Wu, Kaifei Tian, Xuan Guo, Yunming Fang. (2023) Integrating Fermentation Engineering and Organopalladium Chemocatalysis for the Production of Squalene from Biomass-Derived Carbohydrates as the Starting Material. Catalysts, 13 (11): (1392). [10.3390/catal13111392] |
| 3. Guang-Rui Xu, Ning Zhang, Qiyan Sun, Wen Zhang, Zexing Wu, Lei Wang. (2023) Self-supportive Pd0.2Ni58Fe30O11.8 nanowires for solar-driven self-powered water/seawater splitting with large current density. CHEMICAL ENGINEERING JOURNAL, 476 (146778). [10.1016/j.cej.2023.146778] |
| 4. Cuizhen Yang, Tingyao Wang, Chengcheng Li, Haiyan He, Dongming Liu, Huajie Huang. (2023) PdMo Bimetallene Coupled with MXene Nanosheets as Efficient Bifunctional Electrocatalysts for Formic Acid and Methanol Oxidation Reactions. ACS Applied Materials & Interfaces, 15 (42): (49195–49203). [PMID:37843990] [10.1021/acsami.3c10789] |
| 5. Juan Miao, Jingmin Wang, Zhen Lv, Xiaoying Feng, Ning Zhang, Xinquan Zhou, Hang Xu, Xuefeng Wei, Shuge Peng. (2023) Single-atom Pd loaded on nitrogen-doped carbon as a bifunctional catalyst for the electrochemical degradation of 2,4-dichlorophenol. Journal of Environmental Chemical Engineering, 11 (111007). [10.1016/j.jece.2023.111007] |
| 6. Chong Lu, Subrata Panda, Wen Zhu, Yanling Ma, Jianxin Zou. (2024) Enhanced hydrogen sorption properties of uniformly dispersed Pd-decorated three-dimensional (3D) Mg@Pd architecture. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 50 (979). [10.1016/j.ijhydene.2023.08.271] |
| 7. Hongjie Yu, Shaojian Jiang, Wenjie Zhan, Kai Deng, Ziqiang Wang, You Xu, Hongjing Wang, Liang Wang. (2023) Hydrogen-intercalation enhanced the anti-CO poisoning ability of palladium-copper metallene for direct formate fuel cells. Materials Today Physics, 38 (101216). [10.1016/j.mtphys.2023.101216] |
| 8. Kaiyang Xu, Yu Chen, Hua Yang, Yuyan Gan, Lizhi Wu, Li Tan, Yihu Dai, Yu Tang. (2024) Partial hydrogenation of anisole to cyclohexanone in water medium catalyzed by atomically dispersed Pd anchored in the micropores of zeolite. APPLIED CATALYSIS B-ENVIRONMENTAL, 341 (123244). [10.1016/j.apcatb.2023.123244] |
| 9. Nan Lu, Bin Liu, Zhengxin Peng, Jing Sui, Xiaofan Zhang, Yuting Ma, Renhong Li, Xiaoqing Yan. (2024) Interfacial electronic structure modulation between Pd and N-containing support for efficient formic acid dehydrogenation. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 49 (850). [10.1016/j.ijhydene.2023.07.317] |
| 10. Fang Wei, Ting Luo, Yan Wang, Lichun Kong, JiuJu Feng, Zhengquan Li, Ji-Qing Lu, Fa Yang. (2023) Boosting CO2 electroreduction to formate via in-situ formation of ultrathin Bi nanosheets decorated with monodispersed Pd nanoparticles. JOURNAL OF CATALYSIS, 424 (50). [10.1016/j.jcat.2023.05.008] |
| 11. Jiamin Liu, Longhai Zhang, Jiaye Liu, Zhihang Xu, Jiaxi Zhang, Lecheng Liang, Li Du, Huiyu Song, Ye Zhu, Nanwen Li, Zhiming Cui. (2023) Surface engineered PdNFe3 intermetallic electrocatalyst for boosting oxygen reduction in alkaline media. APPLIED CATALYSIS B-ENVIRONMENTAL, 334 (122807). [10.1016/j.apcatb.2023.122807] |
| 12. Lulu Kong, DeZhu Chen, Xiaolong Zhang, Lin Zhou, Yongming Deng, Shaohua Wei. (2023) Controllable Fabrication of Hg–Pd–PdO Heterostructures as Efficient Peroxidase Mimics for Carcinoembryonic Antigen Detection. ACS Applied Nano Materials, 6 (5): (3618–3626). [10.1021/acsanm.2c05373] |
| 13. Runfei Xu, Haoyang Huang, Wenjing Wang, Lei Ding, Qiang Lin, Jinbing Li, Yu Zhang, Yongsheng Han, Jianguo Wang, Xiaohua Lu. (2023) Direct conversion of water to hydrogen peroxide on single electrode towards partial oxidation of propylene. CHEMICAL ENGINEERING JOURNAL, 461 (141748). [10.1016/j.cej.2023.141748] |
| 14. Pengcheng Li, Jingjing Zhu, Hongyu Zhang, Lan Wang, Shulin Wang, Mengting Zhang, Jianping Wu, Lirong Yang, Gang Xu. (2023) Preparation of Coupling Catalyst HamZIF-90@Pd@CALB with Tunable Hollow Structure for Efficient Dynamic Kinetic Resolution of 1-Phenylethylamine. MOLECULES, 28 (3): (922). [PMID:36770588] [10.3390/molecules28030922] |
| 15. Zemeng Dong, Qiyan Sun, Guang-Rui Xu, Zexing Wu, Yanyan Li, Jianping Lai, Guangjiu Li, Lei Wang. (2022) Universal Synthesized Strategy for Amorphous Pd-Based Nanosheets Boosting Ambient Ammonia Electrosynthesis. Small Methods, 7 (1): (2201225). [PMID:36549895] [10.1002/smtd.202201225] |
| 16. Zhijie Zhu, Xu Hu, Xingda An, Mengqi Xiao, Liang Zhang, Chaoran Li, Le He. (2022) Photothermal Catalytic CO2 Hydrogenation with High Activity and Tailored Selectivity Over Monodispersed Pd-Ni Nanoalloys. Chemistry-An Asian Journal, 17 (24): (e202200993). [PMID:36323636] [10.1002/asia.202200993] |
| 17. Xiaolan Li, Yangqi Huang, Zhenyu Chen, Shuqi Hu, Jinliang Zhu, Panagiotis Tsiakaras, Pei Kang Shen. (2023) Novel PtNi nanoflowers regulated by a third element (Rh, Ru, Pd) as efficient multifunctional electrocatalysts for ORR, MOR and HER. CHEMICAL ENGINEERING JOURNAL, 454 (140131). [10.1016/j.cej.2022.140131] |
| 18. Chunxue Zhao, Haihong Yu, Zhiming Liu, Haolin Chen, Xiao Ma, Yiqiao Chen, Ao Liu, Huiqing Zhong, Zhouyi Guo. (2022) Facile synthesis of Au@palladium oxide nano-sunflowers for ultrasensitive surface-enhanced Raman scattering analysis. NEW JOURNAL OF CHEMISTRY, 46 (23): (11195-11201). [10.1039/D2NJ01578A] |
| 19. Yangyang Ren, Baosong Li, Chenhao Lv, Fan Gao, Xiaojing Yang, Lanlan Li, Zunming Lu, Xiaofei Yu, Xinghua Zhang. (2022) Defect-rich PtPdCu flower-like nanoframes with enhanced electrocatalytic activity for methanol oxidation. APPLIED SURFACE SCIENCE, 593 (153404). [10.1016/j.apsusc.2022.153404] |
| 20. Gongguo Zhang, Yingying Wang, Yanyun Ma, Yiqun Zheng, Haifeng Zhang, Mingyu Tang, Yunqian Dai. (2023) Ultrathin samarium-doped palladium nanocrystals with exotic shapes for efficient electrocatalytic ethanol oxidation. CATALYSIS TODAY, 409 (63). [10.1016/j.cattod.2022.03.024] |
| 21. Li Zhijun, Leng Leipeng, Lu Xiaowen, Zhang Mingyang, Xu Qian, Horton J. Hugh, Zhu Junfa. (2022) Single palladium atoms stabilized by β-FeOOH nanorod with superior performance for selective hydrogenation of cinnamaldehyde. Nano Research, 15 (4): (3114-3121). [10.1007/s12274-021-4028-1] |
| 22. Zhijie Zhu, Kai Feng, Chaoran Li, Rui Tang, Mengqi Xiao, Rui Song, Di Yang, Binhang Yan, Le He. (2021) Stabilization of Exposed Metal Nanocrystals in High-Temperature Heterogeneous Catalysis. ADVANCED MATERIALS, 34 (6): (2108727). [PMID:34816506] [10.1002/adma.202108727] |
| 23. Jingjing Zhu, Huaqiang Chen, Lan Wang, Engang Fu, Jianping Wu, Qilei Zhang, Lirong Yang, Gang Xu. (2022) High-efficient dynamic kinetic resolution of amines with a core-shell hollow mesoporous MIL-101@Pd@ZIF-8 nanocatalyst and lipase. MICROPOROUS AND MESOPOROUS MATERIALS, 329 (111490). [10.1016/j.micromeso.2021.111490] |
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| 26. Xiaobo Yang, Xili Tong, Xingchen Liu, Kaixi Li, Nianjun Yang. (2021) Methanol electrooxidation on core-shell Ag@Pdx catalysts. ELECTROCHEMISTRY COMMUNICATIONS, 123 (106917). [10.1016/j.elecom.2021.106917] |
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| 1. Wenjie Xue, Binbin Zhao, Hongxia Liu, Xinqing Chen, Lei Liu. (2024) Ultralow Pd bimetallic catalysts boost (de)hydrogenation for reversible H2 storage. APPLIED CATALYSIS B-ENVIRONMENTAL, 343 (123574). [10.1016/j.apcatb.2023.123574] |
| 2. Cuicui Wu, Kaifei Tian, Xuan Guo, Yunming Fang. (2023) Integrating Fermentation Engineering and Organopalladium Chemocatalysis for the Production of Squalene from Biomass-Derived Carbohydrates as the Starting Material. Catalysts, 13 (11): (1392). [10.3390/catal13111392] |
| 3. Guang-Rui Xu, Ning Zhang, Qiyan Sun, Wen Zhang, Zexing Wu, Lei Wang. (2023) Self-supportive Pd0.2Ni58Fe30O11.8 nanowires for solar-driven self-powered water/seawater splitting with large current density. CHEMICAL ENGINEERING JOURNAL, 476 (146778). [10.1016/j.cej.2023.146778] |
| 4. Cuizhen Yang, Tingyao Wang, Chengcheng Li, Haiyan He, Dongming Liu, Huajie Huang. (2023) PdMo Bimetallene Coupled with MXene Nanosheets as Efficient Bifunctional Electrocatalysts for Formic Acid and Methanol Oxidation Reactions. ACS Applied Materials & Interfaces, 15 (42): (49195–49203). [PMID:37843990] [10.1021/acsami.3c10789] |
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