基本描述

别名	乙酰丙酮钯 \| 2,4-戊二酸钯(II) \| 乙酰丙酮钯(II) \| 双(2,4-戊二酮)钯(II) \| 乙酰丙酮钯(II)盐 \| 乙酰丙酮钯 (II)
英文别名	[Pd(acac)2] \| MFCD00000025 \| Bis(2,4-pentanedionato)palladium(II) \| Palladium(II) acetylacetonate \| Palladium(II) acetylacetonate, 99% \| BIS(2,4-PENTANEDIONATO-O,O')PALLADIUM(II) \| Pd(acac)2 \| Bis(acetylacetonato)palladium(II) \| Palladium(II) acetylaceton
规格或纯度	≥99%
英文名称	Palladium acetylacetonate
储存温度	室温
运输条件	常规运输
产品介绍	溶于苯、甲苯和氯仿。不溶于水。空气中稳定。用于羰基化、低聚化等反应。在芳基羧酸与芳基卤化物的脱羧交叉偶联中使用的催化剂 Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium. Application Guide for Palladium Catalyzed Cross-Coupling Reactions. Product class M-O, Homogeneous Catalysts, Acetylacetonate Ligands Reaction type CH-Activation, Carbonylation, Cyclization, Oligomerization, Oxidation Chemical properties Chemical formula C10H14O4Pd Empirical formula [Pd(acac)2] Molecular weight 304.64 Metal Pd Theoretical metal content 35 Physical state powder Color yellow

名称和识别符

PubChem SID	488195560
EC号	237-859-8
IUPAC Name	(Z)-4-hydroxypent-3-en-2-one;palladium
INCHI	InChI=1S/2C5H8O2.Pd/c21-4(6)3-5(2)7;/h23,6H,1-2H3;/b2*4-3-;
InChi Key	BABLLCDZHABSRT-FDGPNNRMSA-N
Canonical SMILES	CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Pd]
Isomeric SMILES	C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.[Pd]
WGK Germany	2
PubChem CID	5462715
分子量	304.64
Beilstein号	4136188

化学和物理性质

溶解性	Soluble in benzene and chloroform.
敏感性	对光敏感
沸点	300 °C 在 0.1 百帕
熔点	200 - 251 °C
分子量	306.650 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	2
氢键受体数Hydrogen Bond Acceptor Count	4
可旋转键计数Rotatable Bond Count	2
精确质量Exact Mass	306.008 Da
单同位素质量Monoisotopic Mass	306.008 Da
拓扑极表面积Topological Polar Surface Area	74.600 Å²
重原子数Heavy Atom Count	15
形式电荷Formal Charge	0
复杂度Complexity	239.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	2
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	2
共价键合单元计数Covalently-Bonded Unit Count	3

安全和危险性（GHS）

象形图	GHS07
信号词	Warning
危险声明	H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H228: 易燃固体
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P337+P317: 如果眼睛刺激持续：寻求医疗帮助。 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	2
个人防护装备	dust mask type N95 (US),Eyeshields,Gloves

SDS英文版

质量标准

Assay(Pd)	34.4-35.4（%）
Carbon by Elemental Analysis	38.5-40（%）
Oxygen by Elemental Analysi	20.5-21.5（%）
Appearance（P101065)	yellow to yellow-green powder
Infrared spectrum	Conforms to Structure

质量标准

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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找到27个结果

批号(Lot Number)	证书类型	日期	货号
E2519406	分析证书	25-04-21	P101065
E2519407	分析证书	25-04-21	P101065
E2519405	分析证书	25-04-21	P101065
L2423099	分析证书	24-12-16	P101065
L2423251	分析证书	24-12-16	P101065
L2423100	分析证书	24-12-16	P101065
I2402124	分析证书	24-08-26	P101065
I2402125	分析证书	24-08-26	P101065
I2402127	分析证书	24-08-26	P101065
F2414104	分析证书	24-06-03	P101065
F2414106	分析证书	24-06-03	P101065
A2404663	分析证书	23-12-18	P101065
A2404666	分析证书	23-12-18	P101065
G2303110	分析证书	23-06-25	P101065
L2312021	分析证书	23-06-25	P101065
G2303113	分析证书	23-06-25	P101065
G2303114	分析证书	23-06-25	P101065
G2303121	分析证书	23-06-25	P101065
G2303126	分析证书	23-06-25	P101065
L22151122	分析证书	22-11-23	P101065
J2325040	分析证书	22-11-23	P101065
L22151016	分析证书	22-11-23	P101065
L22151048	分析证书	22-11-23	P101065
F2225590	分析证书	22-06-10	P101065
F2225591	分析证书	22-06-10	P101065
C2208331	分析证书	22-02-18	P101065
C2208342	分析证书	22-02-18	P101065

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参考文献

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