基本描述

别名	1,3-环戊二烯基-1,2,3,4,5-五甲基-铑配合物 \| 二氯(五甲基环戊二烯基)铑(II)二聚体 \| 二氯(五甲基环戊二烯基)铑二聚体 \| 五甲基环戊二烯基氯化铑二聚体 \| 四氯双(五甲基环戊二烯基)二铑
英文别名	Chiralyst P618
规格或纯度	99.95% metals basis
英文名称	Pentamethylcyclopentadienylrhodium(III) chloride dimer
储存温度	室温,充氩
运输条件	常规运输
产品介绍	Catalyst for: Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactions Catalyst for: Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactions Product class M-C, Homogeneous Catalysts, Arene/Aryl Ligands Reaction type Hydrogenation, CH-Activation, Transfer Hydrogenation, Oxidation Chemical properties Chemical formula C20H30Cl4Rh2 Empirical formula [Rh(C5Me5)Cl2]2 Molecular weight 618.08 Metal Rh Theoretical metal content 33 Physical state crystalline Color red Metal purity 99.95

名称和识别符

INCHI	1S/2C10H15.4ClH.2Rh/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
InChi Key	QNIVKTTWBMFSBR-UHFFFAOYSA-J
Canonical SMILES	Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
WGK Germany	3
分子量	618.08

化学和物理性质

溶解性	Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
敏感性	空气及湿度敏感
熔点	>300°C

安全和危险性（GHS）

象形图	GHS07
信号词	Warning
危险声明	H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H302+H312+H332: 吞咽，皮肤接触或吸入有害。
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P501: 将内容物/容器处理到。。。 P312: 打电话给毒物中心或医生。。。如果你觉得不舒服 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P337+P313: 如仍觉眼刺激：求医/就诊。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P332+P313: 如发生皮肤刺激：求医/就诊。 P301+P312: 如误吞咽：如感觉不适，呼叫急救中心/医生。 P301+P312+P330: 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口 P302+P352+P312: 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304+P340+P312: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。
WGK Germany	3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

SDS英文版

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此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站?

1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187] [10.1021/acsami.2c18440]
2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064] [10.1016/j.aca.2022.340393]
3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690] [10.1021/acsami.2c11174]
4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216] [10.1002/chem.202201430]
5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li. (2020) Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction. ACS Catalysis, 10 (21): (12976–12986). [10.1021/acscatal.0c03652]
6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang. (2018) g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration. ACS Catalysis, 8 (7): (5664–5674). [10.1021/acscatal.8b00070]

参考文献

1. Ying Zhang, Bin Wei, Hao Liang. (2023) Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization. ACS Applied Materials & Interfaces, 15 (2): (3442–3454). [PMID:36609187] [10.1021/acsami.2c18440]
2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang. (2022) Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications. ANALYTICA CHIMICA ACTA, 1230 (340393). [PMID:36192064] [10.1016/j.aca.2022.340393]
3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li. (2022) Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer. ACS Applied Materials & Interfaces, 14 (34): (38895–38904). [PMID:35986690] [10.1021/acsami.2c11174]
4. Yuanyuan Zhang, Jian Liu. (2022) Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction. CHEMISTRY-A EUROPEAN JOURNAL, 28 (55): (e202201430). [PMID:35758216] [10.1002/chem.202201430]
5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li. (2020) Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction. ACS Catalysis, 10 (21): (12976–12986). [10.1021/acscatal.0c03652]
6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang. (2018) g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration. ACS Catalysis, 8 (7): (5664–5674). [10.1021/acscatal.8b00070]

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货号 (SKU)	包装规格	是否现货
P284028-100mg	100mg	期货
P284028-250mg	250mg	期货
P284028-1g	1g	期货

二氯(五甲基环戊二烯基)合铑(III)二聚体

库存信息

库存信息

库存信息

基本描述

名称和识别符

化学和物理性质

安全和危险性（GHS）

质量标准

质检证书（CoA,COO,BSE/TSE 和分析图谱)

此产品的引用文献

参考文献

溶液计算器

摩尔浓度计算器

稀释计算器

复溶计算器