| 货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
|---|---|---|---|---|
| P283931-500mg |
500mg |
现货  |
| |
| P283931-5g |
5g |
现货 |
|
| 别名 | 乙酸钯 |
|---|---|
| 英文别名 | [Pd(OAc)2]3 | Palladium (II) acetate | SR-01000389719 | EU-0040175 | BCP05504 | Palladium(II) acetate | palladium-(II) acetate | UNII-0LTG3460Y5 | Bis(acetato)palladium | Acetic Acid Palladium(II) Salt | AMY1789 | AC-677 | Diacetatopalladium | Acetic acid |
| 规格或纯度 | ≥99.95% metals basis |
| 英文名称 | Palladium acetate |
| 储存温度 | 室温 |
| 运输条件 | 常规运输 |
| 产品介绍 |
Product class Reaction type
Chemical formula C12H18O12Pd3 Empirical formula [Pd(OAc)2]3 Molecular weight 673.53 Metal Pd Theoretical metal content 47 Physical state powder Color red brown Metal purity 99.95 Applications & references Synthesis of 2-(4-{2-[(2R)-2-Cyclopentyl-5-(5,7-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-2-ylmethyl)-4-hydroxy-6-oxo-3,6-dihydro-2H-pyran-2-yl]-ethyl}-2-fluoro-phenyl)-2-methyl-propionitrile on multikilogram scale using a merging Heck coupling reaction. Compound is an inhibitor of the hepatitis C viral polymerase (HCVP) enzyme.
Reference: Org. Proc. Res. Dev. 2006, 10, 814. (DOI: 10.1021/op0600761) Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.
Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w) Synthesis of the pyrazolopyridinone-based p38 mitogen-activated protein kinase inhibitor including a Suzuki coupling reaction. p38 MAP kinases are intercellular serine/threonine kinases which certainly regulate the production and action of several pro-inflammatory mediators. They are also involved in disease states such as rheumatoid arthritis, Crohn’s diseases and psoriasis.
Reference: Org. Proc. Res. Dev. 2011, 15, 31. (DOI: 10.1021/op100205s) Efficient hydroformylation of aryl triflates.
Reference: Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246) Deacetylation-Diazotation-Heck-Sequence: Carbon-Carbon bond formation with acetanilides as formal leaving groups
Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929) Deacetylation-Diazotation-Suzuki-Sequence: Carbon-Carbon bond formation with acetanilides as formal leaving groups.
Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929) Deacetylation-Diazotation-[2+2+1]-Cycloaddition:
Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929) |
| PubChem SID | 504757612 |
|---|---|
| EC号 | 222-164-4 |
| IUPAC Name | palladium(2+);diacetate |
| INCHI | InChI=1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 |
| InChi Key | YJVFFLUZDVXJQI-UHFFFAOYSA-L |
| Canonical SMILES | CC(=O)[O-].CC(=O)[O-].[Pd+2] |
| Isomeric SMILES | CC(=O)[O-].CC(=O)[O-].[Pd+2] |
| WGK Germany | 3 |
| RTECS | AJ1900000 |
| PubChem CID | 167845 |
| UN Number | 3077 |
| Packing Group | III |
| 分子量 | 224.51 |
| Beilstein号 | 6086766 |
| 熔点 | 216.3-223.7°C |
|---|---|
| 分子量 | 224.510 g/mol |
| XLogP3 | |
| 氢键供体数Hydrogen Bond Donor Count | 0 |
| 氢键受体数Hydrogen Bond Acceptor Count | 4 |
| 可旋转键计数Rotatable Bond Count | 0 |
| 精确质量Exact Mass | 223.93 Da |
| 单同位素质量Monoisotopic Mass | 223.93 Da |
| 拓扑极表面积Topological Polar Surface Area | 80.300 Ų |
| 重原子数Heavy Atom Count | 9 |
| 形式电荷Formal Charge | 0 |
| 复杂度Complexity | 25.500 |
| 同位素原子数Isotope Atom Count | 0 |
| 定义的原子立体中心计数Defined Atom Stereocenter Count | 0 |
| 未定义的原子立体中心计数Undefined Atom Stereocenter Count | 0 |
| 定义的键立体中心计数Defined Bond Stereocenter Count | 0 |
| 未定义的键立体中心计数Undefined Bond Stereocenter Count | 0 |
| 所有立体化学键的总数The total count of all stereochemical bonds | 0 |
| 共价键合单元计数Covalently-Bonded Unit Count | 3 |
| 象形图 | GHS09, GHS05, GHS07 |
|---|---|
| 信号词 | Danger |
| 危险声明 |
H302: 吞食有害 H318: 造成严重的眼睛损伤 H317: 可能引起皮肤过敏反应 H400: 对水生生物有剧毒 H410: 对水生生物有剧毒并具有长期持续影响 |
| 预防措施声明 |
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P272: 被污染的工作服不允许离开工作场所 P333+P313: 如发生皮肤刺激或皮疹：求医/就诊。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P391: 收集溢出物 P330: 漱口 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P301+P317: 如果被吞咽：请寻求医疗帮助。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 |
| WGK Germany | 3 |
| RTECS | AJ1900000 |
| Class | 9 |
| Merck Index | 6991 |
| 个人防护装备 | dust mask type N95 (US),Eyeshields,Gloves |
| Pd(Gravimetric Analysis With Dimethylglyoxime) | 46.2-48.8（%） |
|---|---|
| Purity(Based on Trace Metals Impurities of ICP) | ≥99.95（%） |
| total metallic impurities(by ICP Atomic emission) | ≤500（ppm） |
| Appearance(P283931) | Orange to Brown Powder |
| ICP: Confirms Palladium Component | Confirmed |
| Infrared spectrum | Conforms to Structure |
| NMR Spectrum 1H | Conforms to Structure |
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