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苯基双(2,4,6-三甲基苯甲酰基)氧化膦（BAPO）

苯基双(2,4,6-三甲基苯甲酰基)氧化膦（BAPO）

44篇引用文献

≥97%

CAS编号: 162881-26-7
分子式: [(CH₃)₃C₆H₂CO]₂P(O)C₆H₅
分子量: 418.46
EC号: 423-340-5
MDL号: MFCD01863675
PubChem编号: 164512
PubChem SID: 488188362

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货号 (SKU)	包装规格	是否现货
P138333-25g	25g	现货
P138333-100g	100g	期货
P138333-500g	500g	现货

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基本描述

别名	双酰基膦氧化物
英文别名	Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide, 97%, powder \| NCGC00256655-01 \| A810419 \| D78117 \| bis(2,4,6-trimethylbenzoyl)-phenyl phosphine oxide \| P2312 \| DTXSID8044597 \| FT-0656698 \| UNII-JOV61FMS35 \| SCHEMBL15158 \| bis(2,4,6-trimethylbenzoyl)phen
规格或纯度	≥97%
英文名称	Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide（BAPO）
应用	多功能紫外光引发剂用于不饱和树脂的基团聚合，特别是有色的配方。
储存温度	避光
运输条件	常规运输
产品介绍	用于单酰基-和双酰基氧化膦光引发剂的反应机理研究。多功能紫外光引发剂用于不饱和树脂的基团聚合，特别是有色的配方。苯基双（2,4,6-三甲基苯甲酰基）氧化膦（BAPO）是一种潜在的光引发剂，广泛应用于牙科复合材料的制备。应用：苯基双（2,4,6-三甲基苯甲酰基）氧化膦可用作以下反应的光引发剂：牙科树脂的自由基聚合。与其它引发剂相比，BAPO可改善聚合速率和转化率。制备高温传感器应用中的二乙烯基苯修饰的聚合物基陶瓷材料。 For the reaction mechanism of monoacyl- and bisacylphosphine oxide photoinitiators. Versatile UV photoinitiator for radical polymerization of unsaturated resins, especially pigmented formulations. Phenylbis(2,4,6-trimethylbenzoyl) phosphineoxide (BAPO) is potential photoinitiator widely used in the preparation ofdental composites. Application： Phenylbis(2,4,6-trimethylbenzoyl) phosphine oxide can be used as a photoinitiator for: Radical polymerization of dental resins. BAPO enhances the polymerization rate and conversion compared to other initiators. Preparation of divinylbenzene modified polymer-based ceramic materials for high temperature sensor applications.

名称和识别符

PubChem SID	488188362
EC号	423-340-5
分子类型	小分子
IUPAC Name	[phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone
INCHI	InChI=1S/C26H27O3P/c1-16-12-18(3)23(19(4)13-16)25(27)30(29,22-10-8-7-9-11-22)26(28)24-20(5)14-17(2)15-21(24)6/h7-15H,1-6H3
InChi Key	GUCYFKSBFREPBC-UHFFFAOYSA-N
Canonical SMILES	CC1=CC(=C(C(=C1)C)C(=O)P(=O)(C2=CC=CC=C2)C(=O)C3=C(C=C(C=C3C)C)C)C
Isomeric SMILES	CC1=CC(=C(C(=C1)C)C(=O)P(=O)(C2=CC=CC=C2)C(=O)C3=C(C=C(C=C3C)C)C)C
PubChem CID	164512
分子量	418.46

化学和物理性质

溶解性	solubility acetone, acetonitrile, toluene, and hexanediol diacrylate: soluble
敏感性	对光线敏感
熔点	131-135 °C
分子量	418.500 g/mol
XLogP3	6.000
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	3
可旋转键计数Rotatable Bond Count	5
精确质量Exact Mass	418.17 Da
单同位素质量Monoisotopic Mass	418.17 Da
拓扑极表面积Topological Polar Surface Area	51.200 Å²
重原子数Heavy Atom Count	30
形式电荷Formal Charge	0
复杂度Complexity	610.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS07
信号词	Warning
危险声明	H413: 可能对水生生物造成长期的有害影响 H317: 可能引起皮肤过敏反应
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P501: 将内容物/容器处理到。。。 P272: 被污染的工作服不允许离开工作场所 P333+P313: 如发生皮肤刺激或皮疹：求医/就诊。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。

SDS英文版

质量标准

Melting point	129-133（℃）
Purity(HPLC)	97-100（%）
Appearance（P138333)	white to yellow powder, crystals, and/or chunks
Proton NMR spectrum	Conforms to Structure

质量标准

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找到30个结果

批号(Lot Number)	证书类型	日期	货号
E23291175	分析证书	25-03-05	P138333
B2507211	分析证书	25-01-14	P138333
B2507310	分析证书	25-01-14	P138333
B2507311	分析证书	25-01-14	P138333
G2431414	分析证书	24-07-18	P138333
G2431413	分析证书	24-07-18	P138333
H2205517	分析证书	24-05-11	P138333
D2423438	分析证书	24-04-11	P138333
D2423436	分析证书	24-04-11	P138333
D2423437	分析证书	24-04-11	P138333
A2431301	分析证书	24-01-23	P138333
A2431305	分析证书	24-01-23	P138333
A2431302	分析证书	24-01-23	P138333
A2431303	分析证书	24-01-23	P138333
A2431304	分析证书	24-01-23	P138333
L2318411	分析证书	23-12-07	P138333
L2318412	分析证书	23-12-07	P138333
L2318413	分析证书	23-12-07	P138333
D2010033	分析证书	23-11-15	P138333
K2123573	分析证书	23-09-19	P138333
I2328161	分析证书	23-09-13	P138333
I2328162	分析证书	23-09-13	P138333
I2328163	分析证书	23-09-13	P138333
G2101239	分析证书	23-04-18	P138333
I2002147	分析证书	22-07-11	P138333
H2205393	分析证书	22-06-20	P138333
H2205515	分析证书	22-06-20	P138333
H2205516	分析证书	22-06-20	P138333
C2328146	分析证书	22-06-20	P138333
D2328036	分析证书	22-06-20	P138333

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参考文献

1. Yanli Wan, Yixing Zhao, Yaling Li, Zhenwei Zhang, Sen Li, Tingfang Tian, Li Wang. (2024) Direct in situ photolithography of ultra-stable CsPbBr3 quantum dot arrays based on crosslinking polymerization. Nanoscale, 16 (5): (2504-2512). [PMID:38205675] [10.1039/D3NR04876D]
2. Qi Liu, Lei Li, Gang Liu, Xi He, Yanhua Niu, Guangxian Li. (2024) Dual−crosslinked polyionic liquid polymer electrolyte with optimal balance of ion conductivity and mechanical properties for solid−state lithium metal battery. JOURNAL OF POWER SOURCES, 592 (233897). [10.1016/j.jpowsour.2023.233897]
3. Shaojun Chen, Zhenghe Ren, Ming Chen, Heng Chen, Haitao Zhuo, Haiqiang Zhong. (2023) Self-repairing elastomer based on imidazole π–π stacking interaction. Smart Materials and Structures, 32 (11): (115026). [10.1088/1361-665X/ad026f]
4. Dexing Zhu, Jian Zhang, Qiao Xu, Yaguo Li. (2023) Two-photon polymerization of silica glass diffractive micro-optics with minimal lateral shrinkage. OPTICS EXPRESS, 31 (22): (36037-36047). [PMID:38017762] [10.1364/OE.499528]
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