基本描述

别名	氯化钯(II) \| 二氯化钯
英文别名	PdCl2 \| CCRIS 6263 \| Enplate activator 440 \| Palladium chloride (PdCl2) \| Pd(II) chloride \| Palladium(II) chloride \| Palladium(II) chloride, JIS special grade, >=99.0% \| palladium(II)chloride \| Palladium(II)-chloride \| NCI-C60184 \| palladium-ii-chloride \|
规格或纯度	Pd 59-60%
英文名称	Palladium chloride
储存温度	充氩
运输条件	常规运输
产品介绍	有潮解性，易溶于稀盐酸，能溶于水、乙醇、丙酮和氢溴酸。 1、点滴测定钯、汞、铊和碘，提纯稀有气味，氯化钯试纸检验一氧化碳、检定钴。 2、催化剂，末端烯径（α-烯径）生成甲基酮的氧化催化。 3、通过Wacker反应，在水溶液中用空气作氧化剂，使烯径氧化成醛。 4、用于合成半导体含金属聚合体，该聚合体具有聚吡咯骨架，符合能量最小且接近平面。 Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF4] or [bmim][PF6] (where[bmim]+ = 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol. Palladium catalysts and precursor used as an oxidizing agent and as a source of Pd(0) complexes. Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1 Product class PGM Solids, Chlorides Reaction type Cross Coupling Reactions with Arenes, CH-Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Oxidation Chemical properties Chemical formula Cl2Pd Empirical formula PdCl2 Molecular weight 177.31 Metal Pd Theoretical metal content 60 Physical state powder Color red brown Applications & references Efficient oxidative carboxylation of benzylic C-H bonds via nondirected C(sp³)-H activation forming substituted 2-phenylacetic acid esters and derivatives starting from inexpensive, commercially available starting materials. Reference: J. Am. Chem. Soc. 2012, 134, 9902 (DOI: 10.1021/ja3036459) Efficient Palladium catalyzed hydroformylation of aryl and enol trifluoromethanesulfonates providing α,β-unsaturated aldehydes. Reference: Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246) Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups. Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793)

名称和识别符

EC号	231-115-6
IUPAC Name	dichloropalladium
INCHI	InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2
InChi Key	PIBWKRNGBLPSSY-UHFFFAOYSA-L
Canonical SMILES	Cl[Pd]Cl
Isomeric SMILES	Cl[Pd]Cl
PubChem CID	24290
UN Number	3290
Packing Group	I
分子量	177.33

化学和物理性质

溶解性	Soluble in dilute mineral acids, aqueous metal halides
密度	1.06
敏感性	易吸潮
沸点	2970°C
熔点	678-680 °C
分子量	177.320 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	0
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	175.841 Da
单同位素质量Monoisotopic Mass	175.841 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	3
形式电荷Formal Charge	0
复杂度Complexity	2.800
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS07
信号词	Warning
危险声明	H319: 引起严重眼睛刺激 H317: 可能引起皮肤过敏反应 H303: 要是吞了可能有害 H316: 引起轻微皮肤刺激
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。
Class	6.1, 8
Merck Index	6990
个人防护装备	Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

SDS英文版

质量标准

Purity(Based On Trace Metals Analysis)	99.9-100（%）
Palladium(Pd)	59-60（%）
Total Metallic Impuritie	0-2000（ppm）
Appearance（P105196)	Orange-Brown or Red-Brown Powder
X-Ray Diffraction	Conforms to Structure

质量标准

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批号(Lot Number)	证书类型	日期	货号
G2123189	分析证书	25-05-09	P105196
A2114070	分析证书	24-11-13	P105196
A2114069	分析证书	24-11-13	P105196
D2306554	分析证书	23-01-10	P105196
D2306555	分析证书	23-01-10	P105196
D2306569	分析证书	23-01-10	P105196
J2229410	分析证书	22-09-24	P105196
J2229417	分析证书	22-09-24	P105196
J2229418	分析证书	22-09-24	P105196
L2215357	分析证书	22-09-22	P105196
L2215425	分析证书	22-09-22	P105196
L2215447	分析证书	22-09-22	P105196
L2215448	分析证书	22-09-22	P105196
F2228425	分析证书	22-06-05	P105196
L2419324	分析证书	22-06-05	P105196
F2228426	分析证书	22-06-05	P105196
F2228427	分析证书	22-06-05	P105196
F2228428	分析证书	22-06-05	P105196
C2216034	分析证书	22-02-26	P105196
C2216049	分析证书	22-02-26	P105196
C2216064	分析证书	22-02-26	P105196
H2402060	分析证书	22-02-26	P105196
L2404064	分析证书	22-02-26	P105196

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溶液计算器

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