基本描述

别名	三溴化硼
英文别名	Boron tribromide, ReagentPlus(R), >=99% \| BORON TRIBROMIDE \| Boron tri-bromide \| ILAHWRKJUDSMFH-UHFFFAOYSA- \| Boron tribromide, >=99.99% \| InChI=1/BBr3/c2-1(3)4 \| tribromoboran \| Boron Tribromide (17% in Dichloromethane, ca. 1mol/L) \| B2553 \| Borane, trib
规格或纯度	Reagent Plus，≥99%
英文名称	Boron tribromide
产品介绍	应用作为反应物可用于制备：药物中间体6-硝基-L-多巴具有空间保护的咔唑基硼烷部分的发光聚苯乙烯衍生物通过Wurtz型还原偶联反应得到高质量的硼掺杂石墨烯巯基-(+)-甲基苯丙胺半抗原，用于合成具有改善表位密度的(+)-甲基苯丙胺结合型疫苗微米级有机分子-DNA杂合结构通过亲电芳香硼化反应形成硼烷复合物 5-HT2C受体激动剂具有叔氨基的联苯衍生物，作为β-分泌酶（BACE1）抑制剂以治疗阿尔茨海默病高度近红外区域荧光p-延伸硼氮杂-二吡咯亚甲基部分单元通过甲氧基取代的N-苯乙基酰亚胺的分子内环化形成四氢异喹啉衍生物在由香豆素支架合成 benzopyrano benzopyran 类化合物的反应中用于裂解芳基甲基醚。 General Description Boron tribromide is a strong Lewis acid generally employed in the deprotection of -OH and -NH groups. It is a moisture-sensitive liquid, which is also used to cleave esters or ethers into alkyl bromides. Application Reactant for preparation of: Drug intermediate 6-nitro-L-DOPA Luminescent polystyrene derivatives with sterically protected carbazolylborane moieties High-quality boron-doped graphene via Wurtz-type reductive coupling reaction Mercapto-(+)-methamphetamine haptens for synthesis of (+)-methamphetamine conjugate vaccines with improved epitope densities Micrometer-sized organic molecule-DNA hybrid structures Borane complexes via electrophilic aromatic borylation reactions A 5-HT2C receptor agonist Biphenyl-derivatives possessing tertiary amino groups as β-secretase(BACE1) inhibitors for the treatment of Alzheimer′s disease A highly near-IR region fluorescent p-extended boron aza-dipyrromethene moiety unit Tetrahydroisoquinoline derivatives via intramolecular cyclization of methoxy-substituted N-phenethylimides Used to cleave aryl methyl ethers in a synthesis of a benzopyranobenzopyran from a coumarin scaffold.

名称和识别符

EC号	233-657-9
IUPAC Name	tribromoborane
INCHI	InChI=1S/BBr3/c2-1(3)4
InChi Key	ILAHWRKJUDSMFH-UHFFFAOYSA-N
Canonical SMILES	B(Br)(Br)Br
Isomeric SMILES	B(Br)(Br)Br
WGK Germany	3
RTECS	ED7400000
PubChem CID	25134
UN Number	2692
Packing Group	I
分子量	250.57

化学和物理性质

密度	2.60g/mLat 20°C (lit.)
闪点(℉)	195.8 °F
闪点(℃)	91 °C
沸点	90°C
熔点	-46°C
分子量	250.530 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	0
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	249.762 Da
单同位素质量Monoisotopic Mass	247.764 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	4
形式电荷Formal Charge	0
复杂度Complexity	8.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

一般危化品	一般危化品
象形图	GHS06, GHS05
信号词	Danger
危险声明	H314: 造成严重的皮肤灼伤和眼睛损伤 H300: 吞咽致命 H330: 吸入致命
预防措施声明	P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P284: 如果通风不良，请佩戴呼吸防护装置。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P363: 再次使用之前，请清洗受污染的衣物。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P330: 漱口 P320: 迫切需要特殊治疗（请参阅此标签上的...）。 P301+P316: 如果吞咽：立即寻求紧急医疗救助。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。
WGK Germany	3
RTECS	ED7400000
Class	8, 6.1
个人防护装备	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

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溶液计算器

摩尔浓度计算器

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