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货号 (SKU) 包装规格 是否现货 价格 数量
A196483-250ml
250ml 现货 Stock Image
A196483-1L
1L 现货 Stock Image

基本描述

别名 十二水合硫酸铁铵 | 硫酸铁铵
英文别名 7783-83-7 | Ferric ammonium sulfate dodecahydrate | Iron ammonium sulfate dodecahydrate | Ammonium iron sulfate dodecahydrate | azanium;iron(3+);disulfate;dodecahydrate | Sulfuric acid, ammonium iron(3+) salt (2:1:1), dodecahydrate | MFCD00150004 | 65390568Z5 | Azane;hyd
英文名称 Iron alum indicator solution
运输条件 常规运输
产品介绍


Ammonium iron(III) sulfate dodecahydrate is often employed as an analytical standard, and has been used in a variety of other applications from nanomaterials to general redox reactions. This product is much less affected by oxygen in the air than iron(II) sulfate, making it more desirable for titration purposes, where iron(II) might be oxidized to iron(III). The oxidation of iron(II) to iron(III) is pH dependent, and the reaction occurs more rapidly at higher pH; this product lowers the pH of solutions slightly, thereby preventing oxidation from occurring.
An oxidation resistant analytical standard.

名称和识别符

EC号 233-382-4
IUPAC Name azanium;iron(3+);disulfate;dodecahydrate
INCHI InChI=1S/Fe.H3N.2H2O4S.12H2O/c;;2*1-5(2,3)4;;;;;;;;;;;;/h;1H3;2*(H2,1,2,3,4);12*1H2/q+3;;;;;;;;;;;;;;;/p-3
InChi Key LCPUDZUWZDSKMX-UHFFFAOYSA-K
Canonical SMILES [NH4+].O.O.O.O.O.O.O.O.O.O.O.O.[O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[Fe+3]
Isomeric SMILES [NH4+].O.O.O.O.O.O.O.O.O.O.O.O.[O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[Fe+3]
WGK Germany 3
RTECS WS5900000
关联CAS 10138-04-2
PubChem CID 197097
分子量 482.19

化学和物理性质

密度 1.71
敏感性 对光线敏感,易吸潮
折光率 1.4854
熔点 37°C
分子量 482.200 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count 13
氢键受体数Hydrogen Bond Acceptor Count 20
可旋转键计数Rotatable Bond Count 0
精确质量Exact Mass 482 Da
单同位素质量Monoisotopic Mass 482 Da
拓扑极表面积Topological Polar Surface Area 190.000 Ų
重原子数Heavy Atom Count 24
形式电荷Formal Charge 0
复杂度Complexity 62.200
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 16

安全和危险性(GHS)

象形图 GHS07
信号词 Warning
危险声明

H315: 引起皮肤刺激

H319: 引起严重眼睛刺激

预防措施声明

P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P302+P352: 如皮肤沾染:用水充分清洗。

P321: 特殊处理(请参阅此标签上的...)。

P264: 处理后要彻底洗手。

P362+P364: 脱掉沾污的衣服,清洗后方可重新使用。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P337+P317: 如果眼睛刺激持续:寻求医疗帮助。

P332+P317: 如果出现皮肤刺激:请寻求医疗帮助。

WGK Germany 3
RTECS WS5900000
个人防护装备 dust mask type N95 (US),Eyeshields,Gloves

质量标准

Concentration 7-9(%)
Appearance(A196483) yellow liquid
Sensitivity Test with SCN- become red precipitates

质检证书(CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):
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批号(Lot Number) 证书类型 日期 货号
C2020006 分析证书 24-01-17 A196483

此产品的引用文献

1. Shuo Wang, Xuan Meng, Jing Zhang, Xiangyang Zhang, Sitan Wang, Li Shi, Naiwang Liu.  (2023)  Preparation and Mechanism Study of Green Cyanamide Calcium.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  62  (33): (12985–12998).  [10.1021/acs.iecr.3c01850]
2. Youxin Li, Wan Peng, Yaning Dong, Birong Fan, Weijian Qian, Xiaoxue Ji, Xiong Lu, Donglin Gan, Pingsheng Liu.  (2023)  Mussel-Inspired PEDOT-Incorporated Gelatin-Based Conductive Hydrogel with Flexibility and Electroactivity to Accelerate Wound Healing In Vitro.  ACS Applied Polymer Materials,  (6): (4233–4243).  [10.1021/acsapm.3c00445]
3. Xianghe Meng, Jue Ding, Qin Ye.  (2023)  Silver ion assisted urea complexation for the enrichment of sciadonic acid from Torreya fargesii kernel oil.  BIOCHEMICAL ENGINEERING JOURNAL,  197  (108970).  [10.1016/j.bej.2023.108970]
4. Hong Du, Jing Zheng, Yi Mao, Wen-tao Pan, Yan Zhang, Lin-yu Zhu, Xue-Bo Yin, Min Zhang.  (2023)  Facile Preparation of Magnetic Nitrogen-Doped Carbon Microtubes with Co Nanoparticles for Reduction of 4-Nitrophenol.  ChemistrySelect,  (13): (e202300298).  [10.1002/slct.202300298]
5. Enmin Zong, Xuanren Wang, Lirong Zhang, Jiayao Yang, Xiaohuan Liu.  (2023)  A Recyclable Magnetic Aminated Lignin Supported Zr-La Dual-Metal Hydroxide for Rapid Separation and Highly Efficient Sequestration of Phosphate.  MOLECULES,  28  (7): (2923).  [PMID:37049693] [10.3390/molecules28072923]
6. Enmin Zong, Runfang Fan, Hao Hua, Jiayao Yang, Shengtao Jiang, Jinfeng Dai, Xiaohuan Liu, Pingan Song.  (2023)  A magnetically recyclable lignin-based bio-adsorbent for efficient removal of Congo red from aqueous solution.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,  226  (443).  [PMID:36473527] [10.1016/j.ijbiomac.2022.11.317]
7. Qiaoqiao Wang, Hehe Qin, Jinhong Fan, Haijiao Xie.  (2023)  New insight into the mechanism of ferric hydroxide-based heterogeneous Fenton-like reaction.  JOURNAL OF HAZARDOUS MATERIALS,  443  (130278).  [PMID:36327851] [10.1016/j.jhazmat.2022.130278]
8. Liangchen Long, Yang Yang, Shijie You, Liangliang Wei, Baiyang Chen.  (2022)  Using formaldehyde as a novel chemical actinometer for 185 nm vacuum ultraviolet photon flux quantification in water.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,  432  (114080).  [10.1016/j.jphotochem.2022.114080]
9. Feng Zhu, Xingyun Hu, Linghao Kong, Xianjia Peng.  (2022)  Calcium sulfide-organosilicon complex for sustained release of H2S in strongly acidic wastewater: Synthesis, mechanism and efficiency.  JOURNAL OF HAZARDOUS MATERIALS,  421  (126745).  [PMID:34364206] [10.1016/j.jhazmat.2021.126745]
10. Xiaoji Cao, Mei Fang, Danqi Dong, Beibei Ye, Jiahui Xu, Xuemin Ye, Weimin Mo.  (2020)  Dispersive liquid–liquid extraction based on magnetic Pickering emulsion followed by gas chromatography–tandem mass spectrometry for the simultaneous determination of aldehydes in environmental water samples.  JOURNAL OF SEPARATION SCIENCE,  43  (12): (2401-2408).  [PMID:32160648] [10.1002/jssc.201901150]
11. Ning Xia, Dehua Deng, Xiangsheng Mu, Ang Liu, Jiaxun Xie, Dandan Zhou, Ping Yang, Yun Xing, Lin Liu.  (2020)  Colorimetric immunoassays based on pyrroloquinoline quinone-catalyzed generation of Fe(II)-ferrozine with tris(2-carboxyethyl)phosphine as the reducing reagent.  SENSORS AND ACTUATORS B-CHEMICAL,  306  (127571).  [10.1016/j.snb.2019.127571]
12. Wei Wang, Ai-Lei Xu, Zheng-Chao Li, Yi Li, Shun-Fu Xu, Hua-Chao Sang, Fachao Zhi.  (2019)  Combination of Probiotics and Salvia miltiorrhiza Polysaccharide Alleviates Hepatic Steatosis via Gut Microbiota Modulation and Insulin Resistance Improvement in High Fat-Induced NAFLD Mice.  Diabetes & Metabolism Journal,  44  (2): (336-348).  [PMID:31950772] [10.4093/dmj.2019.0042]
13. Xinqiang Cao, Yingping Huang, Changcun Tang, Jianzhu Wang, David Jonson, Yanfen Fang.  (2020)  Preliminary study on the electrocatalytic performance of an iron biochar catalyst prepared from iron-enriched plants.  Journal of Environmental Sciences,  88  (81).  [PMID:31862082] [10.1016/j.jes.2019.08.004]
14. Gao Hejun, Du Jia, Liao Yunwen.  (2019)  Removal of chromium(VI) and orange II from aqueous solution using magnetic polyetherimide/sugarcane bagasse.  CELLULOSE,  26  (5): (3285-3297).  [10.1007/s10570-019-02301-7]
15. Zhang Dong, Lu Li, Lü Ting, Jin Meiqing, Lin Jun, Liu Xingyuan, Zhao Hongting.  (2018)  Application of a rice husk-derived biochar in soil immobilization of iodide (I−) and iodate (IO3 −).  JOURNAL OF SOILS AND SEDIMENTS,  18  (4): (1540-1547).  [10.1007/s11368-017-1864-4]
16. Azat Ramila, Liu Yan, Li Wei, Kayir Abdurihim, Lin Ding-bo, Zhou Wen-wen, Zheng Xiao-dong.  (2016)  Probiotic properties of lactic acid bacteria isolated from traditionally fermented Xinjiang cheese.  Journal of Zhejiang University-SCIENCE B,  17  (8): (597-609).  [PMID:27487805] [10.1631/jzus.B1500250]
17. Tianlin Zhang, Xiadan Yue, Keren Zhang, Jinghao Li, Caiyian Zhu, Lei Zhang, Wei Chen.  (2016)  Selective adsorption of CuSO4 from mixed sulfate solutions by Cu(II) ion-imprinted polymers containing salicylaldoximes, ammonium cations, and tertiary amino groups.  MATERIALS & DESIGN,  107  (372).  [10.1016/j.matdes.2016.06.054]
18. Xiaoji Cao, Lingxiao Shen, Xuemin Ye, Feifei Zhang, Jiaoyu Chen, Weimin Mo.  (2014)  Ultrasound-assisted magnetic solid-phase extraction based ionic liquid-coated Fe3O4@graphene for the determination of nitrobenzene compounds in environmental water samples.  ANALYST,  139  (8): (1938-1944).  [PMID:24575420] [10.1039/C3AN01937C]
19. Xiaoji Cao, Jiaoyu Chen, Xuemin Ye, Feifei Zhang, Lingxiao Shen, Weimin Mo.  (2013)  Ultrasound-assisted magnetic SPE based on Fe3O4-grafted graphene for the determination of polychlorinated biphenyls in water samples.  JOURNAL OF SEPARATION SCIENCE,  36  (21-22): (3579-3585).  [PMID:24030865] [10.1002/jssc.201300770]

参考文献

1. Shuo Wang, Xuan Meng, Jing Zhang, Xiangyang Zhang, Sitan Wang, Li Shi, Naiwang Liu.  (2023)  Preparation and Mechanism Study of Green Cyanamide Calcium.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  62  (33): (12985–12998).  [10.1021/acs.iecr.3c01850]
2. Youxin Li, Wan Peng, Yaning Dong, Birong Fan, Weijian Qian, Xiaoxue Ji, Xiong Lu, Donglin Gan, Pingsheng Liu.  (2023)  Mussel-Inspired PEDOT-Incorporated Gelatin-Based Conductive Hydrogel with Flexibility and Electroactivity to Accelerate Wound Healing In Vitro.  ACS Applied Polymer Materials,  (6): (4233–4243).  [10.1021/acsapm.3c00445]
3. Xianghe Meng, Jue Ding, Qin Ye.  (2023)  Silver ion assisted urea complexation for the enrichment of sciadonic acid from Torreya fargesii kernel oil.  BIOCHEMICAL ENGINEERING JOURNAL,  197  (108970).  [10.1016/j.bej.2023.108970]
4. Hong Du, Jing Zheng, Yi Mao, Wen-tao Pan, Yan Zhang, Lin-yu Zhu, Xue-Bo Yin, Min Zhang.  (2023)  Facile Preparation of Magnetic Nitrogen-Doped Carbon Microtubes with Co Nanoparticles for Reduction of 4-Nitrophenol.  ChemistrySelect,  (13): (e202300298).  [10.1002/slct.202300298]
5. Enmin Zong, Xuanren Wang, Lirong Zhang, Jiayao Yang, Xiaohuan Liu.  (2023)  A Recyclable Magnetic Aminated Lignin Supported Zr-La Dual-Metal Hydroxide for Rapid Separation and Highly Efficient Sequestration of Phosphate.  MOLECULES,  28  (7): (2923).  [PMID:37049693] [10.3390/molecules28072923]
6. Enmin Zong, Runfang Fan, Hao Hua, Jiayao Yang, Shengtao Jiang, Jinfeng Dai, Xiaohuan Liu, Pingan Song.  (2023)  A magnetically recyclable lignin-based bio-adsorbent for efficient removal of Congo red from aqueous solution.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,  226  (443).  [PMID:36473527] [10.1016/j.ijbiomac.2022.11.317]
7. Qiaoqiao Wang, Hehe Qin, Jinhong Fan, Haijiao Xie.  (2023)  New insight into the mechanism of ferric hydroxide-based heterogeneous Fenton-like reaction.  JOURNAL OF HAZARDOUS MATERIALS,  443  (130278).  [PMID:36327851] [10.1016/j.jhazmat.2022.130278]
8. Liangchen Long, Yang Yang, Shijie You, Liangliang Wei, Baiyang Chen.  (2022)  Using formaldehyde as a novel chemical actinometer for 185 nm vacuum ultraviolet photon flux quantification in water.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,  432  (114080).  [10.1016/j.jphotochem.2022.114080]
9. Feng Zhu, Xingyun Hu, Linghao Kong, Xianjia Peng.  (2022)  Calcium sulfide-organosilicon complex for sustained release of H2S in strongly acidic wastewater: Synthesis, mechanism and efficiency.  JOURNAL OF HAZARDOUS MATERIALS,  421  (126745).  [PMID:34364206] [10.1016/j.jhazmat.2021.126745]
10. Xiaoji Cao, Mei Fang, Danqi Dong, Beibei Ye, Jiahui Xu, Xuemin Ye, Weimin Mo.  (2020)  Dispersive liquid–liquid extraction based on magnetic Pickering emulsion followed by gas chromatography–tandem mass spectrometry for the simultaneous determination of aldehydes in environmental water samples.  JOURNAL OF SEPARATION SCIENCE,  43  (12): (2401-2408).  [PMID:32160648] [10.1002/jssc.201901150]
11. Ning Xia, Dehua Deng, Xiangsheng Mu, Ang Liu, Jiaxun Xie, Dandan Zhou, Ping Yang, Yun Xing, Lin Liu.  (2020)  Colorimetric immunoassays based on pyrroloquinoline quinone-catalyzed generation of Fe(II)-ferrozine with tris(2-carboxyethyl)phosphine as the reducing reagent.  SENSORS AND ACTUATORS B-CHEMICAL,  306  (127571).  [10.1016/j.snb.2019.127571]
12. Wei Wang, Ai-Lei Xu, Zheng-Chao Li, Yi Li, Shun-Fu Xu, Hua-Chao Sang, Fachao Zhi.  (2019)  Combination of Probiotics and Salvia miltiorrhiza Polysaccharide Alleviates Hepatic Steatosis via Gut Microbiota Modulation and Insulin Resistance Improvement in High Fat-Induced NAFLD Mice.  Diabetes & Metabolism Journal,  44  (2): (336-348).  [PMID:31950772] [10.4093/dmj.2019.0042]
13. Xinqiang Cao, Yingping Huang, Changcun Tang, Jianzhu Wang, David Jonson, Yanfen Fang.  (2020)  Preliminary study on the electrocatalytic performance of an iron biochar catalyst prepared from iron-enriched plants.  Journal of Environmental Sciences,  88  (81).  [PMID:31862082] [10.1016/j.jes.2019.08.004]
14. Gao Hejun, Du Jia, Liao Yunwen.  (2019)  Removal of chromium(VI) and orange II from aqueous solution using magnetic polyetherimide/sugarcane bagasse.  CELLULOSE,  26  (5): (3285-3297).  [10.1007/s10570-019-02301-7]
15. Zhang Dong, Lu Li, Lü Ting, Jin Meiqing, Lin Jun, Liu Xingyuan, Zhao Hongting.  (2018)  Application of a rice husk-derived biochar in soil immobilization of iodide (I−) and iodate (IO3 −).  JOURNAL OF SOILS AND SEDIMENTS,  18  (4): (1540-1547).  [10.1007/s11368-017-1864-4]
16. Azat Ramila, Liu Yan, Li Wei, Kayir Abdurihim, Lin Ding-bo, Zhou Wen-wen, Zheng Xiao-dong.  (2016)  Probiotic properties of lactic acid bacteria isolated from traditionally fermented Xinjiang cheese.  Journal of Zhejiang University-SCIENCE B,  17  (8): (597-609).  [PMID:27487805] [10.1631/jzus.B1500250]
17. Tianlin Zhang, Xiadan Yue, Keren Zhang, Jinghao Li, Caiyian Zhu, Lei Zhang, Wei Chen.  (2016)  Selective adsorption of CuSO4 from mixed sulfate solutions by Cu(II) ion-imprinted polymers containing salicylaldoximes, ammonium cations, and tertiary amino groups.  MATERIALS & DESIGN,  107  (372).  [10.1016/j.matdes.2016.06.054]
18. Xiaoji Cao, Lingxiao Shen, Xuemin Ye, Feifei Zhang, Jiaoyu Chen, Weimin Mo.  (2014)  Ultrasound-assisted magnetic solid-phase extraction based ionic liquid-coated Fe3O4@graphene for the determination of nitrobenzene compounds in environmental water samples.  ANALYST,  139  (8): (1938-1944).  [PMID:24575420] [10.1039/C3AN01937C]
19. Xiaoji Cao, Jiaoyu Chen, Xuemin Ye, Feifei Zhang, Lingxiao Shen, Weimin Mo.  (2013)  Ultrasound-assisted magnetic SPE based on Fe3O4-grafted graphene for the determination of polychlorinated biphenyls in water samples.  JOURNAL OF SEPARATION SCIENCE,  36  (21-22): (3579-3585).  [PMID:24030865] [10.1002/jssc.201300770]

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